Features Key features of the Galaxy Core  vs Ace 3 

screen size

The screen technology has also been upgraded to PLS from a regular TFT panel.
Galaxy Core | by GSM Arena (Feb, 2014)

screen resolution

Galaxy Core
960 x 540
Galaxy Ace 3
800 x 480
Pricing and specific regional details will be announced soon.
Galaxy Core | by PocketLint (Feb, 2014)

memory

processor

Galaxy Core
Dual core
Galaxy Ace 3
Dual core
The Samsung Galaxy Core Prime is relatively thin (8.8mm), packs a 4.5" PLS LCD screen with WVGA resolution and runs Android 4.4 KitKat on a quad-core 1.3GHz processor with 1GB of RAM.
Galaxy Core | by GSM Arena (Oct, 2014)

camera resolution

While it's camera department is less impressive it seems like the new Core will compensate with LTE connectivity.
Galaxy Core | by GSM Arena (Oct, 2014)

Differences What are the advantages of each

Back view of Samsung Galaxy Core

Reasons to consider the
Samsung Galaxy Core

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Supports FM radio Yes vs No Somewhat common; Listen to music and news from local radio stations
More battery capacity 2,100 mA·h vs 1,500 mA·h 40% more battery capacity
Bigger screen 4.5" vs 4" Around 15% bigger screen
Faster processor 1.2 GHz vs 1 GHz Around 20% faster processor; run computation-intensive applications, such as photo editing, faster
Records higher def video 1920 x 1080 @ 30 fps vs 1280 x 720 @ 30 fps 2.2x higher def video
Back view of Samsung Galaxy Ace 3

Reasons to consider the
Samsung Galaxy Ace 3

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Is 4G Yes vs No Somewhat common; Supports the fastest, most reliable networks

Specifications Full list of technical specs

screen

Galaxy Core  vs
Ace 3 
Size 4.5" 4"
Resolution 960 x 540 800 x 480
Multitouch N/A Yes
PPI 244 ppi 233 ppi

hardware

Clock speed 1.2 GHz 1 GHz
Number of cores Dual core Dual core
RAM 1 GB 1 GB
Internal storage 8 GB 4 GB
Supported card formats
SDXC
SDHC
SD

photo & video

Camera 5 MP 5 MP
Resolution 5 MP 5 MP
Flash Yes Yes
Secondary camera 0.3 MP 0.3 MP
Video resolution 1920 x 1080 @ 30 fps 1280 x 720 @ 30 fps

cellular

Generation 3G 4G
Networks
LTE (20 Mb/s)
GPRS (0.01 Mb/s)
UMTS (0.38 Mb/s)
LTE Cat4 (150 Mb/s)
LTE Cat 4 (150/)
HSPA (unspecified)
EDGE (0.38 Mb/s)
Unknown (150 Mb/s)
LTE Cat3/4 Uplink (50 Mb/s)
LTE Cat3
HSDPA+ (42.2 Mb/s)
GSM (0.01 Mb/s)

battery

Capacity 2,100 mA·h 1,500 mA·h

form factor

Galaxy Core  vs
Ace 3 
Thickness 9.8 mm 10 mm
Size 66.3 x 132.9 x 9.8 mm 62.7 x 121.2 x 10 mm

sensors

Has an assisted GPS Yes Yes

music

Supports FM radio Yes No

software

Operating system Android 4.2.2 Android 4.2.2
Multitasking Yes Yes
App store Android Market Android Market
Adobe flash support No No
App store size 850,000 apps 850,000 apps

connectivity

Acts as a wi-fi hotspot No No
Supports NFC Yes Yes
Bluetooth Bluetooth v4.0 Bluetooth v4.0
Samsung Galaxy Core
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Samsung Galaxy Ace 3
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